Which Annex of MARPOL contains the regulations for prevention of pollution by oil?

MARPOL Annex I. A revised edition (Resolution MEPC. 117(52), adopted in October 2004) entered into force on 1 January 2007.

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Which MARPOL Annex I regulations contain the conditions for oil and oily water discharges from ships?

If cargo was not discharged in “apparent good order and condition” and there was a claim against the company, what evidence might be useful in resisting the claim?